Denitrogenative Pd/Cu-catalyzed Suzuki-type cross-coupling of Aryltrifluoroborates with Arylhydrazine hydrochlorides in water under room temperature
A water-soluble palladium-catalyzed Suzuki-type cross-coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co-catalyzed denitrogenative reaction gave a ran...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2018
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| In: |
Applied organometallic chemistry
Year: 2017, Volume: 32, Issue: 3 |
| ISSN: | 1099-0739 |
| DOI: | 10.1002/aoc.4203 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1002/aoc.4203 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/aoc.4203 
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| Author Notes: | Guofang Wang, Mengting Meng, Liping Deng, Kai Cheng, Chenze Qi |
| Summary: | A water-soluble palladium-catalyzed Suzuki-type cross-coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co-catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen. |
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| Item Description: | First published: 21 December 2017 Gesehen am 17.06.2019 |
| Physical Description: | Online Resource |
| ISSN: | 1099-0739 |
| DOI: | 10.1002/aoc.4203 |