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Guanidine electron donors and silver halides: interplay and competition between redox, coordination and polymerization reactions

Redox reactions compete with coordination and polymerization reactions when the organic electron donor and ligand, 1,2,4,5-tetrakis(tetramethylguanidino)benzene (1), is dissolved together with silver halides AgX (X = Cl, Br or I) in solvents of different polarity. The complex results obtained for th...

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Bibliographic Details
Main Authors: Emeljanenko, Dimitri (Author) , Horn, Julian (Author) , Kaifer, Elisabeth (Author) , Wadepohl, Hubert (Author) , Himmel, Hans-Jörg (Author)
Format: Article (Journal)
Language:English
Published: 2012
In: European journal of inorganic chemistry
Year: 2011, Issue: 4, Pages: 695-704
ISSN:1099-0682
DOI:10.1002/ejic.201101002
Online Access:Verlag, Volltext: https://doi.org/10.1002/ejic.201101002
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201101002
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Author Notes:Dimitri Emeljanenko, Julian Horn, Elisabeth Kaifer, Hubert Wadepohl, and Hans-Jörg Himmel
Description
Summary:Redox reactions compete with coordination and polymerization reactions when the organic electron donor and ligand, 1,2,4,5-tetrakis(tetramethylguanidino)benzene (1), is dissolved together with silver halides AgX (X = Cl, Br or I) in solvents of different polarity. The complex results obtained for the relatively simple system 1/AgX highlight the importance of solvent effects. A variety of chain polymers have been synthesized in which the guanidine electron-donor building blocks are connected by silver halide clusters of different sizes.
Item Description:First published: 21 December 2011
Gesehen am 08.07.2019
Physical Description:Online Resource
ISSN:1099-0682
DOI:10.1002/ejic.201101002

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