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Synthesis and structural characterization of group 10 metal complexes bearing an amidodiphosphine pincer ligand: Dedicated to Prof. Dr. Alexander C. Filippou on the Occasion of his 60th Birthday

Deprotonation of 3,6-di-tert-butyl-1,8-bis((diisopropyl-phosphanyl)-methyl)-9H-carbazole [(CbzdiphosiPr)H] (1) with LiHMDS and reaction with (cod)PtCl2 yielded the corresponding platinum chloride complex (CbzdiphosiPr)PtCl (2), which was converted quantitatively into the bromide 3 and iodide 4 analo...

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Bibliographic Details
Main Authors: Hartmann, Deborah (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 16 June 2018
In: Zeitschrift für anorganische und allgemeine Chemie
Year: 2018, Volume: 644, Issue: 17, Pages: 1011-1017
ISSN:1521-3749
DOI:10.1002/zaac.201800173
Online Access:Verlag, Volltext: https://doi.org/10.1002/zaac.201800173
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.201800173
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Author Notes:Deborah Hartmann, Hubert Wadepohl, Lutz H. Gade
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Summary:Deprotonation of 3,6-di-tert-butyl-1,8-bis((diisopropyl-phosphanyl)-methyl)-9H-carbazole [(CbzdiphosiPr)H] (1) with LiHMDS and reaction with (cod)PtCl2 yielded the corresponding platinum chloride complex (CbzdiphosiPr)PtCl (2), which was converted quantitatively into the bromide 3 and iodide 4 analogues by treatment with TMS-Hal (Hal = Br, I). Moreover, it was possible to prepare a PtIV species by oxidative addition of CsBr3 to compound 3. Furthermore, the hydride complexes of all group 10 metals were obtained by treatment of compound 1 with the M(0) precursors Ni(cod)2, Pd(PtBu3)2, and Pt(PtBu3)2.
Item Description:Gesehen am 16.09.2019
Physical Description:Online Resource
ISSN:1521-3749
DOI:10.1002/zaac.201800173

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