Benzopyrano-fused N-heterocyclic polyaromatics

Polycyclic heteroaromatic compounds are potentially interesting materials for organic electronic applications. While most of those compounds contain nitrogen or sulfur, oxygen-based structures are much rarer, especially those including annulated pyrane rings. By the utilization of a cascade of Picte...

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Bibliographic Details
Main Authors: Elbert, Sven (Author) , Reinschmidt, Martin (Author) , Baumgärtner, Kevin (Author) , Rominger, Frank (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: 02 January 2018
In: European journal of organic chemistry
Year: 2018, Issue: 4, Pages: 532-536
ISSN:1099-0690
DOI:10.1002/ejoc.201701796
Online Access:Verlag, Volltext: https://doi.org/10.1002/ejoc.201701796
Verlag: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.201701796
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Author Notes:Sven M. Elbert, Martin Reinschmidt, Kevin Baumgärtner, Frank Rominger, Michael Mastalerz
Description
Summary:Polycyclic heteroaromatic compounds are potentially interesting materials for organic electronic applications. While most of those compounds contain nitrogen or sulfur, oxygen-based structures are much rarer, especially those including annulated pyrane rings. By the utilization of a cascade of Pictet-Spengler reactions and thermally induced ipso-substitutions, a series of peri-benzopyrano-fused nitrogen containing polycyclic aromatic compounds was synthesized and their optoelectronic properties investigated by UV/Vis and emission spectroscopy as well as cyclic voltammetry and DFT-calculations.
Item Description:Gesehen am 18.10.2019
Physical Description:Online Resource
ISSN:1099-0690
DOI:10.1002/ejoc.201701796