A nickel-salphen type complex with a heteropicene backbone
Acenes and heteroacenes as well as other larger fused aromatics and heteroaromatics are per se interesting for organic electronics. Among the large variety of such compounds those annulated π systems that bear multidentate complexation sites for transition metals are rare. This is even more true, th...
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
08 May 2018
|
| In: |
Zeitschrift für anorganische und allgemeine Chemie
Year: 2018, Jahrgang: 644, Heft: 14, Pages: 606-610 |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.201800115 |
| Online-Zugang: | Verlag, Volltext: https://doi.org/10.1002/zaac.201800115 Verlag: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.201800115 
|
| Verfasserangaben: | Sven M. Elbert, Frank Rominger, Michael Mastalerz |
| Zusammenfassung: | Acenes and heteroacenes as well as other larger fused aromatics and heteroaromatics are per se interesting for organic electronics. Among the large variety of such compounds those annulated π systems that bear multidentate complexation sites for transition metals are rare. This is even more true, the larger the π systems are. Picene is an alternating angular annulated π system consisting of five benzene rings. Here, the synthesis of a heteropicene that contains both thiophene and pyridine rings is introduced, whereas the nitrogen atoms are arranged in a phenanthroline subunit to which phenol units are connected, forming a tetradentate ligand. The complexation of NiII by this ligand is described and analysed by single-crystal X-ray diffraction as well as UV/Vis spectroscopy. |
|---|---|
| Beschreibung: | Gesehen am 21.10.2019 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.201800115 |