Mixed iodonium-, phosphonium-, arsonium-, sulfoniumdiazonium ylides in reactions with nucleophiles
The reactions of mixed ylides containing a diazonium fragment and an "onium" group of different nature with nucleophiles were studied. In the iodonium-diazonium and sulfoniumdiazonium ylide, the nucleophile first of all substitutes the iodonium and sulfonium group. A series of hetaryl-subs...
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| Main Authors: | , , , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
15 April 2019
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| In: |
Russian chemical bulletin
Year: 2019, Volume: 68, Issue: 2, Pages: 284-292 |
| ISSN: | 1573-9171 |
| DOI: | 10.1007/s11172-019-2384-8 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1007/s11172-019-2384-8
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| Author Notes: | T.A. Podrugina, A.S. Pavlova, D.S. Vinogradov, M.V. Shuvalov, I.D. Potapov, I.I. Levina, A.V. Mironov, and R. Gleiter |
| Summary: | The reactions of mixed ylides containing a diazonium fragment and an "onium" group of different nature with nucleophiles were studied. In the iodonium-diazonium and sulfoniumdiazonium ylide, the nucleophile first of all substitutes the iodonium and sulfonium group. A series of hetaryl-substituted phosphazines was obtained by a one-pot process of nucleophilic substitution in a diazonium-iodonium ylide with subsequent nucleophilic addition of triarylphosphine at the diazo group. |
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| Item Description: | Gesehen am 12.11.2019 |
| Physical Description: | Online Resource |
| ISSN: | 1573-9171 |
| DOI: | 10.1007/s11172-019-2384-8 |