Nucleophilic neutral Diborane(4) compounds with sp3-sp3-hybridized Boron atoms
Borylation reactions with diborane(4) compounds are of key importance in modern synthetic chemistry. Generally, sp2-sp2-hybridized diborane(4) compounds are used for this purpose; these can be regarded as boryl-substituted boranes and consequently react as electrophiles. In contrast, the chemistry o...
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
07 Febrary 2018
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European journal of inorganic chemistry
Year: 2018, Heft: 20/21, Pages: 2139-2154 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201800031 |
| Online-Zugang: | Verlag, Volltext: https://doi.org/10.1002/ejic.201800031 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201800031 
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| Verfasserangaben: | Hans-Jörg Himmel |
| Zusammenfassung: | Borylation reactions with diborane(4) compounds are of key importance in modern synthetic chemistry. Generally, sp2-sp2-hybridized diborane(4) compounds are used for this purpose; these can be regarded as boryl-substituted boranes and consequently react as electrophiles. In contrast, the chemistry of nucleophilic, electron-rich sp3-sp3-hybridized diborane(4) compounds is a very underdeveloped research field. This review highlights some aspects of this chemistry, showing that it offers great new opportunities for diboration and boron-boron coupling reactions. The discussion focusses primarily on especially nucleophilic doubly guanidinate-bridged diborane(4) compounds. |
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| Beschreibung: | First published: 07 Febrary 2018 Gesehen am 15.01.2020 sp3: Zahl 3 ist hochgestellt |
| Beschreibung: | Online Resource |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201800031 |