Color-selective printed organic photodiodes for filterless multichannel visible light communication

Future lightweight, flexible, and wearable electronics will employ visible-light-communication schemes to interact within indoor environments. Organic photodiodes are particularly well suited for such technologies as they enable chemically tailored optoelectronic performance and fabrication by print...

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Main Authors: Strobel, Noah (Author) , Droseros, Nikolaos (Author) , Köntges, Wolfgang (Author) , Seiberlich, Mervin (Author) , Pietsch, Manuel (Author) , Schlißke, Stefan (Author) , Lindheimer, Felix (Author) , Schröder, Rasmus R. (Author) , Lemmer, Uli (Author) , Pfannmöller, Martin (Author) , Banerji, Natalie (Author) , Hernandez‐Sosa, Gerardo (Author)
Format: Article (Journal)
Language:English
Published: 18 February 2020
In: Advanced materials
Year: 2020, Volume: 32, Issue: 12
ISSN:1521-4095
DOI:10.1002/adma.201908258
Online Access:Resolving-System, Volltext: https://doi.org/10.1002/adma.201908258
Verlag: https://onlinelibrary.wiley.com/doi/abs/10.1002/adma.201908258
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Author Notes:Noah Strobel, Nikolaos Droseros, Wolfgang Köntges, Mervin Seiberlich, Manuel Pietsch, Stefan Schlisske, Felix Lindheimer, Rasmus R. Schröder, Uli Lemmer, Martin Pfannmöller, Natalie Banerji, and Gerardo Hernandez‐Sosa
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Summary:Future lightweight, flexible, and wearable electronics will employ visible-light-communication schemes to interact within indoor environments. Organic photodiodes are particularly well suited for such technologies as they enable chemically tailored optoelectronic performance and fabrication by printing techniques on thin and flexible substrates. However, previous methods have failed to address versatile functionality regarding wavelength selectivity without increasing fabrication complexity. This work introduces a general solution for printing wavelength-selective bulk-heterojunction photodetectors through engineering of the ink formulation. Nonfullerene acceptors are incorporated in a transparent polymer donor matrix to narrow and tune the response in the visible range without optical filters or light-management techniques. This approach effectively decouples the optical response from the viscoelastic ink properties, simplifying process development. A thorough morphological and spectroscopic investigation finds excellent charge-carrier dynamics enabling state-of-the-art responsivities >102 mA W−1 and cutoff frequencies >1.5 MHz. Finally, the color selectivity and high performance are demonstrated in a filterless visible-light-communication system capable of demultiplexing intermixed optical signals.
Item Description:Online version of record before inclusion in an issue
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Physical Description:Online Resource
ISSN:1521-4095
DOI:10.1002/adma.201908258