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Borohydride intermediates pave the way for magnesium-catalysed enantioselective ketone reduction

A magnesium precatalyst for the highly enantioselective hydro-boration of CO bonds is reported. The mechanistic basis of the unprecedented selectivity of this transformation has been investi-gated experimentally by isolation of catalytic intermediates and theoretically by DFT calculations. The facil...

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Main Authors: Vasilenko, Vladislav (Author) , Blasius, Clemens K. (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 2020
In: Chemical communications
Year: 2019, Volume: 56, Issue: 8, Pages: 1203-1206
ISSN:1364-548X
DOI:10.1039/C9CC09111D
Online Access:Verlag, Volltext: https://doi.org/10.1039/C9CC09111D
Verlag: https://pubs.rsc.org/en/content/articlelanding/2020/cc/c9cc09111d
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Author Notes:Vladislav Vasilenko, Clemens K. Blasius, Hubert Wadepohl and Lutz H. Gade

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