Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers

Tunnelling currents through molecular junctions are affected by quantum interference effects, but understanding the factors leading to them remains a challenge. Here the authors show that through-space conjugation in self-assembled monolayers leads to conformation-dependent quantum interference that...

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Main Authors: Carlotti, Marco (Author) , Kovalchuk, Andrii (Author) , Wächter, Tobias (Author) , Qiu, Xinkai (Author) , Zharnikov, Michael (Author) , Chiechi, Ryan C. (Author)
Format: Article (Journal)
Language:English
Published: 20 December 2016
In: Nature Communications
Year: 2016, Volume: 7
ISSN:2041-1723
DOI:10.1038/ncomms13904
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1038/ncomms13904
Verlag, lizenzpflichtig, Volltext: https://www.nature.com/articles/ncomms13904
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Author Notes:Marco Carlotti, Andrii Kovalchuk, Tobias Wächter, Xinkai Qiu, Michael Zharnikov & Ryan C. Chiechi
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Summary:Tunnelling currents through molecular junctions are affected by quantum interference effects, but understanding the factors leading to them remains a challenge. Here the authors show that through-space conjugation in self-assembled monolayers leads to conformation-dependent quantum interference that suppresses conductivity.
Item Description:Gesehen am 29.04.2020
Physical Description:Online Resource
ISSN:2041-1723
DOI:10.1038/ncomms13904