Synthesis and chiral resolution of C3-Symmetric tribenzotriquinacenes
The synthesis and chiral resolution of a C3-symmetric triaminotribenzotriquinacene is reported. Both enantiomers were obtained in good yields and excellent enantiomeric purity by selective precipitation of their monodibenzoyltartrate salts. Conversion of the enantiopure (M)-triaminotribenzotriquinac...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
08 August 2016
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| In: |
European journal of organic chemistry
Year: 2016, Issue: 26, Pages: 4470-4472 |
| ISSN: | 1099-0690 |
| DOI: | 10.1002/ejoc.201600890 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejoc.201600890 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201600890 
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| Author Notes: | Daniel Beaudoin, Frank Rominger, and Michael Mastalerz |
| Summary: | The synthesis and chiral resolution of a C3-symmetric triaminotribenzotriquinacene is reported. Both enantiomers were obtained in good yields and excellent enantiomeric purity by selective precipitation of their monodibenzoyltartrate salts. Conversion of the enantiopure (M)-triaminotribenzotriquinacene into a C3-symmetric triiodide highlights the usefulness of this compound as a starting point for the preparation of other enantiopure C3-symmetric tribenzotriquinacene derivatives, which may find application as building blocks for the preparation of chiral molecules in the nanosize regime. |
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| Item Description: | Im Titel die 3 ist tiefgestellt Gesehen am 04.05.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1099-0690 |
| DOI: | 10.1002/ejoc.201600890 |