Cover Image

A versatile hard-soft N/S-ligand for metal coordination and cluster formation

Deprotonation of the thialdiphosphazane [SPH(μ-NtBu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-NtBu)]22−, which is valence-isoelectronic with the widely-used [RN-P(μ-NR)]22− ligand. Structural studies show that the new ligand has adaptable hard-soft character with respect to the...

Full description

Saved in:
Bibliographic Details
Main Authors: Benson, Callum (Author) , Plajer, Alex (Author) , García-Rodríguez, Raúl (Author) , Bond, Andrew D. (Author) , Singh, Sanjay (Author) , Gade, Lutz H. (Author) , Wright, Dominic S. (Author)
Format: Article (Journal)
Language:English
Published: 06 Jul 2016
In: Chemical communications
Year: 2016, Volume: 52, Issue: 62, Pages: 9683-9686
ISSN:1364-548X
DOI:10.1039/C6CC04805F
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C6CC04805F
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc04805f
Get full text
Author Notes:Callum G. M. Benson, Alex J. Plajer, Raúl García-Rodríguez, Andrew D. Bond, Sanjay Singh, Lutz H. Gade, and Dominic S. Wright
Description
Summary:Deprotonation of the thialdiphosphazane [SPH(μ-NtBu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-NtBu)]22−, which is valence-isoelectronic with the widely-used [RN-P(μ-NR)]22− ligand. Structural studies show that the new ligand has adaptable hard-soft character with respect to the coordinated metal centre and that its multidentate nature can be exploited to construct large cage architectures.
Item Description:Gesehen am 06.05.2020
Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/C6CC04805F

Similar Items