A stable π-conjugated singlet biradical

A large polycyclic hydrocarbon with a singlet biradical ground state has been obtained by the combined effects of topology and electron-accepting aromatic substituents, which stabilize its open-shell singlet state.

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Bibliographic Details
Main Authors: Hinkel, Felix Peter (Author) , Freudenberg, Jan (Author) , Bunz, Uwe H. F. (Author)
Format: Article (Journal)
Language:English
Published: 27 June 2016
In: Angewandte Chemie. International edition
Year: 2016, Volume: 55, Issue: 34, Pages: 9830-9832
ISSN:1521-3773
DOI:10.1002/anie.201605490
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201605490
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201605490
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Author Notes:Felix Hinkel, Jan Freudenberg, Uwe H.F. Bunz
Description
Summary:A large polycyclic hydrocarbon with a singlet biradical ground state has been obtained by the combined effects of topology and electron-accepting aromatic substituents, which stabilize its open-shell singlet state.
Item Description:Gesehen am 14.05.2020
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.201605490