Excitonic states in Narrow armchair graphene nanoribbons on gold surfaces

Narrow graphene nanoribbons (GNRs) exhibit electronic and optical properties that are not present in extended graphene. Most importantly, they possess band gaps in the order of a few electron volts, which has been subject to numerous studies. Here we report on the experimental observation of exction...

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Bibliographic Details
Main Authors: Bronner, Christopher (Author) , Gerbert, David (Author) , Broska, Alexander (Author) , Tegeder, Petra (Author)
Format: Article (Journal)
Language:English
Published: October 28, 2016
In: The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2016, Volume: 120, Issue: 45, Pages: 26168-26172
ISSN:1932-7455
DOI:10.1021/acs.jpcc.6b10834
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.jpcc.6b10834
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Author Notes:Christopher Bronner, David Gerbert, Alexander Broska, and Petra Tegeder
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Summary:Narrow graphene nanoribbons (GNRs) exhibit electronic and optical properties that are not present in extended graphene. Most importantly, they possess band gaps in the order of a few electron volts, which has been subject to numerous studies. Here we report on the experimental observation of exctionic states in the band gap of N = 7 armchair GNRs (7-GNR) on Au(111) and Au(788) using energy- and angle-resolved two-photon photoemission spectroscopy. Thereby, an exciton binding energy in the 7-GNR on Au(111) of 160 ± 60 meV has been determined. On the stepped Au(788) surface, the exciton binding energy is in the same range.
Item Description:Gesehen am 20.05.2020
Physical Description:Online Resource
ISSN:1932-7455
DOI:10.1021/acs.jpcc.6b10834