Emissive polyelectrolytes as interlayer for color tuning and electron injection in solution-processed light-emitting devices

Herein we present a solution-processed hybrid device architecture combining organic light-emitting diodes (OLEDs) and light-emitting electrochemical cells (LECs) in a bilayer architecture. The LEC interlayer promotes the charge injection from an air-stable Ag cathode as well as permits the color tun...

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Hauptverfasser: Tekoglu, Serpil (VerfasserIn) , Petzoldt, Martin (VerfasserIn) , Stolz, Sebastian (VerfasserIn) , Bunz, Uwe H. F. (VerfasserIn) , Lemmer, Uli (VerfasserIn) , Hamburger, Manuel (VerfasserIn) , Hernandez-Sosa, Gerardo (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: [2016]
In: ACS applied materials & interfaces
Year: 2016, Jahrgang: 8, Heft: 11, Pages: 7320-7325
ISSN:1944-8252
DOI:10.1021/acsami.6b00665
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acsami.6b00665
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Verfasserangaben:Serpil Tekoglu, Martin Petzoldt, Sebastian Stolz, Uwe H. F. Bunz, Uli Lemmer, Manuel Hamburger, and Gerardo Hernandez-Sosa
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Zusammenfassung:Herein we present a solution-processed hybrid device architecture combining organic light-emitting diodes (OLEDs) and light-emitting electrochemical cells (LECs) in a bilayer architecture. The LEC interlayer promotes the charge injection from an air-stable Ag cathode as well as permits the color tuning of the device emission. To this end, we used an alcohol-soluble anionic polyfluorene derivative, the properties of which were investigated by absorption and photoluminescence spectroscopy as well as by cyclic voltammetry. The bilayer device exhibited operating voltages ∼6 V and a color tuning of the emission spectrum dependent on the LEC interlayer thickness. The hybrid devices presented a color emission ranging from the yellow (x = 0.39, y = 0.47) toward the green region (x = 0.29, y = 0.4) of the Commission Internationale de I’Eclairage (CIE) 1931 chromaticity diagram.
Beschreibung:Gesehen am 20.05.2020
Beschreibung:Online Resource
ISSN:1944-8252
DOI:10.1021/acsami.6b00665