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Bisalkynylated 3,6-diiminocyclohexa-1,4-diene-1,4-diamine

Reduction of bis(benzothiadiazol) by LiAlH4/CuI gives diethynylated diaminobenzoquinoneimine. This building block accesses novel targets in a one-step condensation reaction with different ortho-quinones, resulting in unexpected rearrangement products. The compounds are characterized by their photoph...

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Bibliographic Details
Main Authors: Biegger, Philipp (Author) , Schaffroth, Manuel (Author) , Brödner, Kerstin (Author) , Tverskoy, Olena (Author) , Rominger, Frank (Author) , Bunz, Uwe H. F. (Author)
Format: Article (Journal)
Language:English
Published: 21 July 2015
In: Chemical communications
Year: 2015, Volume: 51, Issue: 80, Pages: 14844-14847
ISSN:1364-548X
DOI:10.1039/C5CC05427C
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5CC05427C
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc05427c
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Author Notes:Philipp Biegger, Manuel Schaffroth, Kerstin Brödner, Olena Tverskoy, Frank Rominger and Uwe H.F. Bunz
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Summary:Reduction of bis(benzothiadiazol) by LiAlH4/CuI gives diethynylated diaminobenzoquinoneimine. This building block accesses novel targets in a one-step condensation reaction with different ortho-quinones, resulting in unexpected rearrangement products. The compounds are characterized by their photophysical and electrochemical data as well as quantum chemical calculations.
Item Description:Gesehen am 25.05.2020
Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/C5CC05427C

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