Synthesis and properties of the strained alkene perfluorobicyclo[2.2.0]hex-1(4)-ene
The title fluoroalkene has been generated by dehalogenation of dibromide and diiodide precursors and trapped in situ. retro-Diels-Alder reaction of its adduct with N-benzylpyrrole has made the alkene available in high yield and purity. In sharp contrast to its extremely labile hydrocarbon counterpar...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
January 9, 2015
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| In: |
The journal of organic chemistry
Year: 2015, Volume: 80, Issue: 3, Pages: 1523-1532 |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/jo502456h |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jo502456h
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| Author Notes: | Christopher P. Junk, Yigang He, Yin Zhang, Joshua R. Smith, Rolf Gleiter, Steven R. Kass, Jerry P. Jasinski, and David M. Lemal |
| Summary: | The title fluoroalkene has been generated by dehalogenation of dibromide and diiodide precursors and trapped in situ. retro-Diels-Alder reaction of its adduct with N-benzylpyrrole has made the alkene available in high yield and purity. In sharp contrast to its extremely labile hydrocarbon counterpart, the fluoroalkene is very stable yet highly reactive. Its characterization includes its electron affinity, photoelectron spectrum, and the previously reported structure determination by electron diffraction. |
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| Item Description: | Gesehen am 17.06.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/jo502456h |