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Synthesis and reactivity of an Ir(I) carbonyl complex bearing a carbazolide-bis(NHC) pincer ligand

Synthesis of the new iridium NHC pincer complexes [Ir(bimca)(CO)] (3a) and [Ir(bimcaEt)(CO)] (3b) is realized by salt metathesis of in situ generated [Li(bimca)] (2) with Ir(I) carbonyl precursors. In the case of Vaskas complex [IrCl(CO)(PPh3)2] we isolated the Ir(III) hydrido complex (4). Reactivit...

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Bibliographic Details
Main Authors: Seyboldt, Alexander (Author) , Wucher, Barbara (Author) , Alles, Maria (Author) , Rominger, Frank (Author) , Maichle-Mössmer, Cäcilia (Author) , Kunz, Doris (Author)
Format: Article (Journal)
Language:English
Published: 2015
In: Journal of organometallic chemistry
Year: 2014, Volume: 775, Pages: 202-208
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2014.10.045
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jorganchem.2014.10.045
Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X14005300
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Author Notes:Alexander Seyboldt, Barbara Wucher, Maria Alles, Frank Rominger, Cäcilia Maichle-Mössmer, Doris Kunz
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Summary:Synthesis of the new iridium NHC pincer complexes [Ir(bimca)(CO)] (3a) and [Ir(bimcaEt)(CO)] (3b) is realized by salt metathesis of in situ generated [Li(bimca)] (2) with Ir(I) carbonyl precursors. In the case of Vaskas complex [IrCl(CO)(PPh3)2] we isolated the Ir(III) hydrido complex (4). Reactivity studies of Ir complex 3a towards allyl halides show the ready formation of η1 coordinated allyl ligands at the Ir(III) center in all cases.
Item Description:Available online 8 November 2014
Gesehen am 16.06.2020
Physical Description:Online Resource
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2014.10.045

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