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Synthesis and reactivity of an Ir(I) carbonyl complex bearing a carbazolide-bis(NHC) pincer ligand

Synthesis of the new iridium NHC pincer complexes [Ir(bimca)(CO)] (3a) and [Ir(bimcaEt)(CO)] (3b) is realized by salt metathesis of in situ generated [Li(bimca)] (2) with Ir(I) carbonyl precursors. In the case of Vaskas complex [IrCl(CO)(PPh3)2] we isolated the Ir(III) hydrido complex (4). Reactivit...

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Main Authors: Seyboldt, Alexander (Author) , Wucher, Barbara (Author) , Alles, Maria (Author) , Rominger, Frank (Author) , Maichle-Mössmer, Cäcilia (Author) , Kunz, Doris (Author)
Format: Article (Journal)
Language:English
Published: 2015
In: Journal of organometallic chemistry
Year: 2014, Volume: 775, Pages: 202-208
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2014.10.045
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jorganchem.2014.10.045
Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X14005300
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Author Notes:Alexander Seyboldt, Barbara Wucher, Maria Alles, Frank Rominger, Cäcilia Maichle-Mössmer, Doris Kunz

MARC

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