Synthesis of para-aryl-substituted salicyldialdehydes
Abstract para-Substituted salicyldialdehydes are versatile molecular building blocks for porous organic cages, fluorescent dyes, spirobenzopyrans, homooxacalixarenes, dinuclear metal complexes, macrocycles, and cryptands. To date, no procedures for the synthesis of para-aryl-substituted salicyldiald...
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| Main Authors: | , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
[2015]
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| In: |
European journal of organic chemistry
Year: 2015, Issue: 15, Pages: 3274-3285 |
| ISSN: | 1099-0690 |
| DOI: | 10.1002/ejoc.201500228 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejoc.201500228 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201500228 
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| Author Notes: | Dennis Reinhard, Ludger Schöttner, Victor Brosius, Frank Rominger, and Michael Mastalerz |
| Summary: | Abstract para-Substituted salicyldialdehydes are versatile molecular building blocks for porous organic cages, fluorescent dyes, spirobenzopyrans, homooxacalixarenes, dinuclear metal complexes, macrocycles, and cryptands. To date, no procedures for the synthesis of para-aryl-substituted salicyldialdehydes have been reported, which would broaden the scope of the above-mentioned topics, especially in the field of sensors and dyes, because the aromatic π systems can be enlarged and absorption or fluorescent events can be fine-tuned by various substituents. Herein, two synthetic routes to para-aryl-substituted salicyldialdehydes with both electron-withdrawing and -donating aromatic units are reported. |
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| Item Description: | Gesehen am 17.06.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1099-0690 |
| DOI: | 10.1002/ejoc.201500228 |