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Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalact...

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Bibliographic Details
Main Authors: Stieber, S. Chantal E. (Author) , Huguet, Núria (Author) , Kageyama, Takeharu (Author) , Jevtovikj, Ivana (Author) , Ariyananda, Piyal (Author) , Gordillo, Alvaro (Author) , Schunk, Stephan A. (Author) , Rominger, Frank (Author) , Hofmann, Peter (Author) , Limbach, Michael (Author)
Format: Article (Journal)
Language:English
Published: 3 June 2015
In: Chemical communications
Year: 2015, Volume: 51, Issue: 54, Pages: 10907-10909
ISSN:1364-548X
DOI:10.1039/C5CC01932J
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5CC01932J
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc01932j
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Author Notes:S. Chantal E. Stieber, Núria Huguet, Takeharu Kageyama, Ivana Jevtovikj, Piyal Ariyananda, Alvaro Gordillo, Stephan A. Schunk, Frank Rominger, Peter Hofmann and Michael Limbach
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Summary:We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.
Item Description:Gesehen am 23.06.2020
Im Titel ist "2" in CO2 tiefgestellt
Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/C5CC01932J

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