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Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalact...

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Hauptverfasser: Stieber, S. Chantal E. (VerfasserIn) , Huguet, Núria (VerfasserIn) , Kageyama, Takeharu (VerfasserIn) , Jevtovikj, Ivana (VerfasserIn) , Ariyananda, Piyal (VerfasserIn) , Gordillo, Alvaro (VerfasserIn) , Schunk, Stephan A. (VerfasserIn) , Rominger, Frank (VerfasserIn) , Hofmann, Peter (VerfasserIn) , Limbach, Michael (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 3 June 2015
In: Chemical communications
Year: 2015, Jahrgang: 51, Heft: 54, Pages: 10907-10909
ISSN:1364-548X
DOI:10.1039/C5CC01932J
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5CC01932J
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc01932j
Volltext
Verfasserangaben:S. Chantal E. Stieber, Núria Huguet, Takeharu Kageyama, Ivana Jevtovikj, Piyal Ariyananda, Alvaro Gordillo, Stephan A. Schunk, Frank Rominger, Peter Hofmann and Michael Limbach
Beschreibung
Zusammenfassung:We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.
Beschreibung:Gesehen am 23.06.2020
Im Titel ist "2" in CO2 tiefgestellt
Beschreibung:Online Resource
ISSN:1364-548X
DOI:10.1039/C5CC01932J

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