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5,5′-Diamino-BIPHEP ligands bearing small selector units for non-covalent binding of chiral analytes in solution

A dynamic axially chiral BIPHEP-ligand with 3,5-dichlorobenzoyl amide selector units for non-covalent binding of phenylalanine derivatives has been developed. Interaction studies in solution were performed with rhodium(I) complexes under exclusion of the metal being involved in binding. (Rax, SPhe)...

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Bibliographic Details
Main Authors: Storch, Golo (Author) , Siebert, Max (Author) , Rominger, Frank (Author) , Trapp, Oliver (Author)
Format: Article (Journal)
Language:English
Published: 4 September 2015
In: Chemical communications
Year: 2015, Volume: 51, Issue: 86, Pages: 15665-15668
ISSN:1364-548X
DOI:10.1039/C5CC06306J
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5CC06306J
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc06306j
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Author Notes:G. Storch, M. Siebert, F. Rominger and O. Trapp
Description
Summary:A dynamic axially chiral BIPHEP-ligand with 3,5-dichlorobenzoyl amide selector units for non-covalent binding of phenylalanine derivatives has been developed. Interaction studies in solution were performed with rhodium(I) complexes under exclusion of the metal being involved in binding. (Rax, SPhe) and (Sax, SPhe) adducts were observed as significantly separated species in NMR spectroscopy.
Item Description:Gesehen am 24.06.2020
Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/C5CC06306J

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