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5,5′-Diamino-BIPHEP ligands bearing small selector units for non-covalent binding of chiral analytes in solution

A dynamic axially chiral BIPHEP-ligand with 3,5-dichlorobenzoyl amide selector units for non-covalent binding of phenylalanine derivatives has been developed. Interaction studies in solution were performed with rhodium(I) complexes under exclusion of the metal being involved in binding. (Rax, SPhe)...

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Hauptverfasser: Storch, Golo (VerfasserIn) , Siebert, Max (VerfasserIn) , Rominger, Frank (VerfasserIn) , Trapp, Oliver (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 4 September 2015
In: Chemical communications
Year: 2015, Jahrgang: 51, Heft: 86, Pages: 15665-15668
ISSN:1364-548X
DOI:10.1039/C5CC06306J
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5CC06306J
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc06306j
Volltext
Verfasserangaben:G. Storch, M. Siebert, F. Rominger and O. Trapp
Beschreibung
Zusammenfassung:A dynamic axially chiral BIPHEP-ligand with 3,5-dichlorobenzoyl amide selector units for non-covalent binding of phenylalanine derivatives has been developed. Interaction studies in solution were performed with rhodium(I) complexes under exclusion of the metal being involved in binding. (Rax, SPhe) and (Sax, SPhe) adducts were observed as significantly separated species in NMR spectroscopy.
Beschreibung:Gesehen am 24.06.2020
Beschreibung:Online Resource
ISSN:1364-548X
DOI:10.1039/C5CC06306J

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