Cover Image

Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading

Understanding of the electric transport through surface-anchored metal-organic frameworks (SURMOFs) is important both from a fundamental perspective as well as with regards to possible future applications in electronic devices. To address this mostly unexplored subject, we integrated a series of rep...

Full description

Saved in:
Bibliographic Details
Main Authors: Liu, Jianxi (Author) , Wächter, Tobias (Author) , Irmler, Andreas (Author) , Weidler, Peter G. (Author) , Gliemann, Hartmut (Author) , Pauly, Fabian (Author) , Mugnaini, Veronica (Author) , Zharnikov, Michael (Author) , Wöll, Christof (Author)
Format: Article (Journal)
Language:English
Published: April 15, 2015
In: ACS applied materials & interfaces
Year: 2015, Volume: 7, Issue: 18, Pages: 9824-9830
ISSN:1944-8252
DOI:10.1021/acsami.5b01792
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/acsami.5b01792
Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/acsami.5b01792
Get full text
Author Notes:Jianxi Liu, Tobias Wächter, Andreas Irmler, Peter G. Weidler, Hartmut Gliemann, Fabian Pauly, Veronica Mugnaini, Michael Zharnikov, and Christof Wöll

MARC

LEADER 00000caa a2200000 c 4500
001 1702689026
003 DE-627
005 20230426085733.0
007 cr uuu---uuuuu
008 200626s2015 xx |||||o 00| ||eng c
024 7 |a 10.1021/acsami.5b01792  |2 doi 
035 |a (DE-627)1702689026 
035 |a (DE-599)KXP1702689026 
035 |a (OCoLC)1341341715 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Liu, Jianxi  |e VerfasserIn  |0 (DE-588)1075620406  |0 (DE-627)833554654  |0 (DE-576)444419691  |4 aut 
245 1 0 |a Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading  |c Jianxi Liu, Tobias Wächter, Andreas Irmler, Peter G. Weidler, Hartmut Gliemann, Fabian Pauly, Veronica Mugnaini, Michael Zharnikov, and Christof Wöll 
264 1 |c April 15, 2015 
300 |a 7 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 26.06.2020 
520 |a Understanding of the electric transport through surface-anchored metal-organic frameworks (SURMOFs) is important both from a fundamental perspective as well as with regards to possible future applications in electronic devices. To address this mostly unexplored subject, we integrated a series of representative SURMOF thin films, formed by copper nodes and trimesic acid and known as HKUST-1, in a mercury-drop-based tunneling junction. Although the transport properties of these SURMOFs are analogous to those of hybrid metal-organic molecular wires, manifested by a very low value of the tunneling decay constant (β ≈ 0.006 Å-1), they are at the same time found to be consistent with a linear increase of resistance with film thickness. Upon loading of SURMOF pores with ferrocene (Fc), a noticeable increase in transport current was observed. A transport model and ab initio electronic structure calculations were used to reveal a hopping transport mechanism and to relate the changes upon Fc loading to those of the electronic and vibrational structures of the SURMOF films. 
700 1 |a Wächter, Tobias  |e VerfasserIn  |0 (DE-588)1126460737  |0 (DE-627)88093204X  |0 (DE-576)484503928  |4 aut 
700 1 |a Irmler, Andreas  |e VerfasserIn  |4 aut 
700 1 |a Weidler, Peter G.  |e VerfasserIn  |4 aut 
700 1 |a Gliemann, Hartmut  |e VerfasserIn  |4 aut 
700 1 |a Pauly, Fabian  |e VerfasserIn  |4 aut 
700 1 |a Mugnaini, Veronica  |e VerfasserIn  |4 aut 
700 1 |a Zharnikov, Michael  |e VerfasserIn  |0 (DE-588)1118537629  |0 (DE-627)872019810  |0 (DE-576)479525889  |4 aut 
700 1 |a Wöll, Christof  |e VerfasserIn  |4 aut 
773 0 8 |i Enthalten in  |a American Chemical Society  |t ACS applied materials & interfaces  |d Washington, DC : Soc., 2009  |g 7(2015), 18, Seite 9824-9830  |h Online-Ressource  |w (DE-627)587139617  |w (DE-600)2467494-1  |w (DE-576)299311139  |x 1944-8252  |7 nnas 
773 1 8 |g volume:7  |g year:2015  |g number:18  |g pages:9824-9830  |g extent:7  |a Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading 
856 4 0 |u https://doi.org/10.1021/acsami.5b01792  |x Resolving-System  |x Verlag  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://pubs.acs.org/doi/10.1021/acsami.5b01792  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20200626 
993 |a Article 
994 |a 2015 
998 |g 1118537629  |a Zharnikov, Michael  |m 1118537629:Zharnikov, Michael  |d 120000  |d 120300  |e 120000PZ1118537629  |e 120300PZ1118537629  |k 0/120000/  |k 1/120000/120300/  |p 8 
998 |g 1126460737  |a Wächter, Tobias  |m 1126460737:Wächter, Tobias  |d 120000  |d 120300  |e 120000PW1126460737  |e 120300PW1126460737  |k 0/120000/  |k 1/120000/120300/  |p 2 
999 |a KXP-PPN1702689026  |e 3691451195 
BIB |a Y 
SER |a journal 
JSO |a {"language":["eng"],"note":["Gesehen am 26.06.2020"],"physDesc":[{"extent":"7 S."}],"relHost":[{"recId":"587139617","id":{"zdb":["2467494-1"],"eki":["587139617"],"issn":["1944-8252"]},"pubHistory":["1.2009 -"],"name":{"displayForm":["American Chemical Society"]},"part":{"issue":"18","pages":"9824-9830","year":"2015","text":"7(2015), 18, Seite 9824-9830","extent":"7","volume":"7"},"type":{"bibl":"periodical","media":"Online-Ressource"},"titleAlt":[{"title":"Applied materials & interfaces"}],"title":[{"title":"ACS applied materials & interfaces","title_sort":"ACS applied materials & interfaces"}],"origin":[{"dateIssuedKey":"2009","publisherPlace":"Washington, DC","dateIssuedDisp":"2009-","publisher":"Soc."}],"corporate":[{"display":"American Chemical Society","roleDisplay":"VerfasserIn","role":"aut"}],"note":["Gesehen am 27.08.2020"],"physDesc":[{"extent":"Online-Ressource"}],"disp":"American Chemical SocietyACS applied materials & interfaces","language":["eng"]}],"origin":[{"dateIssuedKey":"2015","dateIssuedDisp":"April 15, 2015"}],"title":[{"title":"Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading","title_sort":"Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading"}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"person":[{"family":"Liu","given":"Jianxi","roleDisplay":"VerfasserIn","display":"Liu, Jianxi","role":"aut"},{"role":"aut","given":"Tobias","roleDisplay":"VerfasserIn","display":"Wächter, Tobias","family":"Wächter"},{"role":"aut","family":"Irmler","given":"Andreas","roleDisplay":"VerfasserIn","display":"Irmler, Andreas"},{"role":"aut","given":"Peter G.","roleDisplay":"VerfasserIn","display":"Weidler, Peter G.","family":"Weidler"},{"role":"aut","display":"Gliemann, Hartmut","roleDisplay":"VerfasserIn","given":"Hartmut","family":"Gliemann"},{"family":"Pauly","roleDisplay":"VerfasserIn","given":"Fabian","display":"Pauly, Fabian","role":"aut"},{"role":"aut","family":"Mugnaini","roleDisplay":"VerfasserIn","display":"Mugnaini, Veronica","given":"Veronica"},{"role":"aut","roleDisplay":"VerfasserIn","given":"Michael","display":"Zharnikov, Michael","family":"Zharnikov"},{"role":"aut","family":"Wöll","display":"Wöll, Christof","roleDisplay":"VerfasserIn","given":"Christof"}],"name":{"displayForm":["Jianxi Liu, Tobias Wächter, Andreas Irmler, Peter G. Weidler, Hartmut Gliemann, Fabian Pauly, Veronica Mugnaini, Michael Zharnikov, and Christof Wöll"]},"id":{"eki":["1702689026"],"doi":["10.1021/acsami.5b01792"]},"recId":"1702689026"} 
SRT |a LIUJIANXIWELECTRICTR1520 

Similar Items