Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading
Understanding of the electric transport through surface-anchored metal-organic frameworks (SURMOFs) is important both from a fundamental perspective as well as with regards to possible future applications in electronic devices. To address this mostly unexplored subject, we integrated a series of rep...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
April 15, 2015
|
| In: |
ACS applied materials & interfaces
Year: 2015, Jahrgang: 7, Heft: 18, Pages: 9824-9830 |
| ISSN: | 1944-8252 |
| DOI: | 10.1021/acsami.5b01792 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/acsami.5b01792 Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/acsami.5b01792 
|
| Verfasserangaben: | Jianxi Liu, Tobias Wächter, Andreas Irmler, Peter G. Weidler, Hartmut Gliemann, Fabian Pauly, Veronica Mugnaini, Michael Zharnikov, and Christof Wöll |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1702689026 | ||
| 003 | DE-627 | ||
| 005 | 20230426085733.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200626s2015 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/acsami.5b01792 |2 doi | |
| 035 | |a (DE-627)1702689026 | ||
| 035 | |a (DE-599)KXP1702689026 | ||
| 035 | |a (OCoLC)1341341715 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Liu, Jianxi |e VerfasserIn |0 (DE-588)1075620406 |0 (DE-627)833554654 |0 (DE-576)444419691 |4 aut | |
| 245 | 1 | 0 | |a Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading |c Jianxi Liu, Tobias Wächter, Andreas Irmler, Peter G. Weidler, Hartmut Gliemann, Fabian Pauly, Veronica Mugnaini, Michael Zharnikov, and Christof Wöll |
| 264 | 1 | |c April 15, 2015 | |
| 300 | |a 7 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 26.06.2020 | ||
| 520 | |a Understanding of the electric transport through surface-anchored metal-organic frameworks (SURMOFs) is important both from a fundamental perspective as well as with regards to possible future applications in electronic devices. To address this mostly unexplored subject, we integrated a series of representative SURMOF thin films, formed by copper nodes and trimesic acid and known as HKUST-1, in a mercury-drop-based tunneling junction. Although the transport properties of these SURMOFs are analogous to those of hybrid metal-organic molecular wires, manifested by a very low value of the tunneling decay constant (β ≈ 0.006 Å-1), they are at the same time found to be consistent with a linear increase of resistance with film thickness. Upon loading of SURMOF pores with ferrocene (Fc), a noticeable increase in transport current was observed. A transport model and ab initio electronic structure calculations were used to reveal a hopping transport mechanism and to relate the changes upon Fc loading to those of the electronic and vibrational structures of the SURMOF films. | ||
| 700 | 1 | |a Wächter, Tobias |e VerfasserIn |0 (DE-588)1126460737 |0 (DE-627)88093204X |0 (DE-576)484503928 |4 aut | |
| 700 | 1 | |a Irmler, Andreas |e VerfasserIn |4 aut | |
| 700 | 1 | |a Weidler, Peter G. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Gliemann, Hartmut |e VerfasserIn |4 aut | |
| 700 | 1 | |a Pauly, Fabian |e VerfasserIn |4 aut | |
| 700 | 1 | |a Mugnaini, Veronica |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zharnikov, Michael |e VerfasserIn |0 (DE-588)1118537629 |0 (DE-627)872019810 |0 (DE-576)479525889 |4 aut | |
| 700 | 1 | |a Wöll, Christof |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |a American Chemical Society |t ACS applied materials & interfaces |d Washington, DC : Soc., 2009 |g 7(2015), 18, Seite 9824-9830 |h Online-Ressource |w (DE-627)587139617 |w (DE-600)2467494-1 |w (DE-576)299311139 |x 1944-8252 |7 nnas |
| 773 | 1 | 8 | |g volume:7 |g year:2015 |g number:18 |g pages:9824-9830 |g extent:7 |a Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading |
| 856 | 4 | 0 | |u https://doi.org/10.1021/acsami.5b01792 |x Resolving-System |x Verlag |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://pubs.acs.org/doi/10.1021/acsami.5b01792 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200626 | ||
| 993 | |a Article | ||
| 994 | |a 2015 | ||
| 998 | |g 1118537629 |a Zharnikov, Michael |m 1118537629:Zharnikov, Michael |d 120000 |d 120300 |e 120000PZ1118537629 |e 120300PZ1118537629 |k 0/120000/ |k 1/120000/120300/ |p 8 | ||
| 998 | |g 1126460737 |a Wächter, Tobias |m 1126460737:Wächter, Tobias |d 120000 |d 120300 |e 120000PW1126460737 |e 120300PW1126460737 |k 0/120000/ |k 1/120000/120300/ |p 2 | ||
| 999 | |a KXP-PPN1702689026 |e 3691451195 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"relHost":[{"note":["Gesehen am 27.08.2020"],"titleAlt":[{"title":"Applied materials & interfaces"}],"pubHistory":["1.2009 -"],"part":{"year":"2015","issue":"18","text":"7(2015), 18, Seite 9824-9830","extent":"7","pages":"9824-9830","volume":"7"},"title":[{"title":"ACS applied materials & interfaces","title_sort":"ACS applied materials & interfaces"}],"corporate":[{"display":"American Chemical Society","role":"aut"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"physDesc":[{"extent":"Online-Ressource"}],"language":["eng"],"id":{"issn":["1944-8252"],"zdb":["2467494-1"],"eki":["587139617"]},"origin":[{"publisherPlace":"Washington, DC","dateIssuedDisp":"2009-","publisher":"Soc.","dateIssuedKey":"2009"}],"name":{"displayForm":["American Chemical Society"]},"recId":"587139617","disp":"American Chemical SocietyACS applied materials & interfaces"}],"note":["Gesehen am 26.06.2020"],"name":{"displayForm":["Jianxi Liu, Tobias Wächter, Andreas Irmler, Peter G. Weidler, Hartmut Gliemann, Fabian Pauly, Veronica Mugnaini, Michael Zharnikov, and Christof Wöll"]},"recId":"1702689026","id":{"doi":["10.1021/acsami.5b01792"],"eki":["1702689026"]},"origin":[{"dateIssuedKey":"2015","dateIssuedDisp":"April 15, 2015"}],"language":["eng"],"physDesc":[{"extent":"7 S."}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"person":[{"given":"Jianxi","role":"aut","family":"Liu","display":"Liu, Jianxi"},{"display":"Wächter, Tobias","role":"aut","given":"Tobias","family":"Wächter"},{"display":"Irmler, Andreas","role":"aut","given":"Andreas","family":"Irmler"},{"family":"Weidler","given":"Peter G.","role":"aut","display":"Weidler, Peter G."},{"display":"Gliemann, Hartmut","family":"Gliemann","role":"aut","given":"Hartmut"},{"role":"aut","given":"Fabian","family":"Pauly","display":"Pauly, Fabian"},{"display":"Mugnaini, Veronica","family":"Mugnaini","given":"Veronica","role":"aut"},{"role":"aut","given":"Michael","family":"Zharnikov","display":"Zharnikov, Michael"},{"given":"Christof","role":"aut","family":"Wöll","display":"Wöll, Christof"}],"title":[{"title":"Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading","title_sort":"Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading"}]} | ||
| SRT | |a LIUJIANXIWELECTRICTR1520 | ||