Coverage-driven dissociation of azobenzene on Cu(111): a route towards defined surface functionalization
We investigate the surface-catalyzed dissociation of the archetypal molecular switch azobenzene on the Cu(111) surface. Based on X-ray photoelectron spectroscopy, normal incidence X-ray standing waves and density functional theory calculations a detailed picture of the coverage-induced formation of...
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| Main Authors: | , , , , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
28 August 2015
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| In: |
Chemical communications
Year: 2015, Volume: 51, Issue: 83, Pages: 15324-15327 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C5CC05003K |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5CC05003K Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc05003k 
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| Author Notes: | Martin Willenbockel, Reinhard J. Maurer, Christopher Bronner, Michael Schulze, Benjamin Stadtmüller, Serguei Soubatch, Petra Tegeder, Karsten Reuter and F. Stefan Tautz |
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| 520 | |a We investigate the surface-catalyzed dissociation of the archetypal molecular switch azobenzene on the Cu(111) surface. Based on X-ray photoelectron spectroscopy, normal incidence X-ray standing waves and density functional theory calculations a detailed picture of the coverage-induced formation of phenyl nitrene from azobenzene is presented. Furthermore, a comparison to the azobenzene/Ag(111) interface provides insight into the driving force behind the dissociation on Cu(111). The quantitative decay of azobenzene paves the way for the creation of a defect free, covalently bonded monolayer. Our work suggests a route of surface functionalization via suitable azobenzene derivatives and the on surface synthesis concept, allowing for the creation of complex immobilized molecular systems. | ||
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