Paving the way to novel phosphorus-based architectures: a noncatalyzed protocol to access six-membered heterocycles
Phosphorus-based heterocycles provide access to materials with properties that are inaccessible from all-carbon architectures. The unique hybridization of phosphorus gives rise to electron-accepting capacities, a large variety of coordination reactions, and the possibility of controlling the electro...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
[2015]
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| In: |
Angewandte Chemie. International edition
Year: 2015, Volume: 54, Issue: 52, Pages: 15872-15875 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201507960 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201507960 Verlag, lizenzpflichtig, Volltext: https://pericles.pericles-prod.literatumonline.com/doi/abs/10.1002/anie.201507960 
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| Author Notes: | Carlos Romero‐Nieto, Alicia López‐Andarias, Carolina Egler‐Lucas, Florian Gebert, Jens-Peter Neus, Oliver Pilgram |
| Summary: | Phosphorus-based heterocycles provide access to materials with properties that are inaccessible from all-carbon architectures. The unique hybridization of phosphorus gives rise to electron-accepting capacities, a large variety of coordination reactions, and the possibility of controlling the electronic properties through phosphorus postfunctionalization. Herein, we describe a new noncatalyzed synthetic protocol to prepare fused six-membered phosphorus heterocycles. In particular, we report the synthesis of novel phosphaphenalenes. These fused systems exhibit the benefits of both five- and six-membered phosphorus heterocycles and enable a series of versatile postfunctionalization reactions. This work thus opens up new horizons in the field of conjugated materials. |
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| Item Description: | Gesehen am 02.07.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201507960 |