Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI)
Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed...
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| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
2015
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| In: |
Chemical communications
Year: 2014, Volume: 51, Issue: 25, Pages: 5402-5405 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C4CC08718F |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C4CC08718F Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c4cc08718f |
| Author Notes: | Sean D. Woodall, Adam N. Swinburne, Nidhu lal Banik, Andrew Kerridge, Poppy Di Pietro, Christian Adam, Peter Kaden and Louise S. Natrajan |
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| 520 | |a Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed or a sum of the two. | ||
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