Synthesis of adipic aldehyde by n-selective hydroformylation of 4-pentenal
Several phosphine and phosphite ligands were tested in the hydroformylation of 4-pentenal to adipic aldehyde, a versatile starting material for industrially very relevant compounds. By varying the ligand structure we were able to increase the selectivity toward adipic aldehyde to >95%. Additional...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
August 5, 2015
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| In: |
Organometallics
Year: 2015, Volume: 34, Issue: 16, Pages: 4102-4108 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/acs.organomet.5b00538 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1021/acs.organomet.5b00538
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| Author Notes: | Jaroslaw Mormul, Michael Mulzer, Tobias Rosendahl, Frank Rominger, Michael Limbach, and Peter Hofmann |
| Summary: | Several phosphine and phosphite ligands were tested in the hydroformylation of 4-pentenal to adipic aldehyde, a versatile starting material for industrially very relevant compounds. By varying the ligand structure we were able to increase the selectivity toward adipic aldehyde to >95%. Additionally, two molecular structures of important catalytic intermediates [(bisphosphite)RhH(CO)2] and one structure of a previously unknown catalyst decomposition product were obtained. |
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| Item Description: | Gesehen am 13.07.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/acs.organomet.5b00538 |