Synthesis of adipic aldehyde by n-selective hydroformylation of 4-pentenal
Several phosphine and phosphite ligands were tested in the hydroformylation of 4-pentenal to adipic aldehyde, a versatile starting material for industrially very relevant compounds. By varying the ligand structure we were able to increase the selectivity toward adipic aldehyde to >95%. Additional...
Gespeichert in:
| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
August 5, 2015
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| In: |
Organometallics
Year: 2015, Jahrgang: 34, Heft: 16, Pages: 4102-4108 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/acs.organomet.5b00538 |
| Online-Zugang: | Verlag, Volltext: https://doi.org/10.1021/acs.organomet.5b00538
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| Verfasserangaben: | Jaroslaw Mormul, Michael Mulzer, Tobias Rosendahl, Frank Rominger, Michael Limbach, and Peter Hofmann |
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| 520 | |a Several phosphine and phosphite ligands were tested in the hydroformylation of 4-pentenal to adipic aldehyde, a versatile starting material for industrially very relevant compounds. By varying the ligand structure we were able to increase the selectivity toward adipic aldehyde to >95%. Additionally, two molecular structures of important catalytic intermediates [(bisphosphite)RhH(CO)2] and one structure of a previously unknown catalyst decomposition product were obtained. | ||
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