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Synthesis of fully substituted 3-formyl-4-iodofurans via a gold(I)-catalyzed oxidation/1,2-alkynyl migration/cyclization/Iodination cascade

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A highly efficient gold(I)-catalyzed cascade reaction for the synthesis of fully substituted 3-formyl-4-iodofurans has been developed. Mechanistic investigations indicate a reaction pathway that involves a direct iodination reaction of the organogold intermediate via functionalization of the AuC(sp...

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Bibliographic Details
Main Authors: Wang, Tao (Author) , Shi, Shuai (Author) , Rudolph, Matthias (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: 20 June 2014
In: Advanced synthesis & catalysis
Year: 2014, Volume: 356, Issue: 10, Pages: 2337-2342
ISSN:1615-4169
DOI:10.1002/adsc.201400356
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201400356
Verlag, lizenzpflichtig, Volltext: https://www.onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201400356
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Author Notes:Tao Wang, Shuai Shi, Matthias Rudolph, and A. Stephen K. Hashmi
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Summary:A highly efficient gold(I)-catalyzed cascade reaction for the synthesis of fully substituted 3-formyl-4-iodofurans has been developed. Mechanistic investigations indicate a reaction pathway that involves a direct iodination reaction of the organogold intermediate via functionalization of the AuC(sp2) bond, instead of a direct iodination of the 3-formylfurans.
Item Description:Gesehen am 07.08.2020
Physical Description:Online Resource
ISSN:1615-4169
DOI:10.1002/adsc.201400356

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