Synthesis of fully substituted 3-formyl-4-iodofurans via a gold(I)-catalyzed oxidation/1,2-alkynyl migration/cyclization/Iodination cascade
A highly efficient gold(I)-catalyzed cascade reaction for the synthesis of fully substituted 3-formyl-4-iodofurans has been developed. Mechanistic investigations indicate a reaction pathway that involves a direct iodination reaction of the organogold intermediate via functionalization of the AuC(sp...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
20 June 2014
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| In: |
Advanced synthesis & catalysis
Year: 2014, Jahrgang: 356, Heft: 10, Pages: 2337-2342 |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201400356 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201400356 Verlag, lizenzpflichtig, Volltext: https://www.onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201400356 
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| Verfasserangaben: | Tao Wang, Shuai Shi, Matthias Rudolph, and A. Stephen K. Hashmi |
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| 520 | |a A highly efficient gold(I)-catalyzed cascade reaction for the synthesis of fully substituted 3-formyl-4-iodofurans has been developed. Mechanistic investigations indicate a reaction pathway that involves a direct iodination reaction of the organogold intermediate via functionalization of the AuC(sp2) bond, instead of a direct iodination of the 3-formylfurans. | ||
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