Synthesis of soluble, alkyne-substituted trideca- and hexadeca-starphenes
Abstract Two literature-known TIPS-ethynyl-dibromoacenes were prepared and employed to synthesize cyclotrimers by using Yamamoto coupling conditions. Two large, well-soluble starphenes were isolated in good yields. Crystallographic characterization verifies the triangular shape and shows significant...
Gespeichert in:
| Hauptverfasser: | , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
August 11, 2014
|
| In: |
Chemistry - a European journal
Year: 2014, Jahrgang: 20, Heft: 40, Pages: 12725-12728 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201403697 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201403697 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201403697 |
| Verfasserangaben: | Elias C. Rüdiger, Michael Porz, Manuel Schaffroth, Frank Rominger, and Uwe H.F. Bunz |
| Zusammenfassung: | Abstract Two literature-known TIPS-ethynyl-dibromoacenes were prepared and employed to synthesize cyclotrimers by using Yamamoto coupling conditions. Two large, well-soluble starphenes were isolated in good yields. Crystallographic characterization verifies the triangular shape and shows significant differences in crystal packing. |
|---|---|
| Beschreibung: | Gesehen am 07.08.2020 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201403697 |