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Coulomb explosion imaged cryptochiral (R,R)-2,3-dideuterooxirane: unambiguous access to the absolute configuration of (+)-glyceraldehyde

Abstract The absolute configuration of (R,R)-2,3-dideuterooxirane, which has been independently determined using Coulomb explosion imaging, has been unambiguously chemically correlated with the stereochemical key reference (+)-glyceraldehyde. This puts the absolute configuration of D(+)-glyceraldehy...

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Main Authors: Zawatzky, Kerstin (Author) , Herwig, Philipp (Author) , Grieser, Manfred (Author) , Heber, Oded (Author) , Jordon-Thaden, Brandon (Author) , Krantz, Claude (Author) , Novotný, Oldřich (Author) , Repnow, Roland (Author) , Schurig, Volker (Author) , Schwalm, Dirk (Author) , Vager, Zeev (Author) , Wolf, Andreas (Author) , Kreckel, Holger (Author) , Trapp, Oliver (Author)
Format: Article (Journal)
Language:English
Published: March 6, 2014
In: Chemistry - a European journal
Year: 2014, Volume: 20, Issue: 19, Pages: 5555-5558
ISSN:1521-3765
DOI:10.1002/chem.201400296
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201400296
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201400296
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Author Notes:Kerstin Zawatzky, Philipp Herwig, Manfred Grieser, Oded Heber, Brandon Jordon-Thaden, Claude Krantz, Oldřich Novotný, Roland Repnow, Volker Schurig, Dirk Schwalm, Zeev Vager, Andreas Wolf, Holger Kreckel, and Oliver Trapp
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Summary:Abstract The absolute configuration of (R,R)-2,3-dideuterooxirane, which has been independently determined using Coulomb explosion imaging, has been unambiguously chemically correlated with the stereochemical key reference (+)-glyceraldehyde. This puts the absolute configuration of D(+)-glyceraldehyde on firm experimental grounds.
Item Description:Gesehen am 25.08.2020
Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201400296

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