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Zirconium and hafnium hydrazinediido half-sandwich complexes: synthesis and reactivity

The hydrazinediido complexes [Cp*M(NxylN)(NNPh2)(dmap)] (M = Zr, 3a; M = Hf, 3b; NxylN = 2-(N-xylylamino)pyrrolinate) have been synthesized, and their reactivity has been investigated. Both complexes were prepared from [Cp*M(NxylN)Cl2] (1a,b) and [Cp*M(NxylN)(NHNPh2)Cl] (2a,b), respectively, as prec...

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Bibliographic Details
Main Authors: Schweizer, Peter Dominik (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: March 18, 2014
In: Organometallics
Year: 2014, Volume: 33, Issue: 7, Pages: 1726-1739
ISSN:1520-6041
DOI:10.1021/om500087s
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/om500087s
Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/om500087s
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Author Notes:Peter D. Schweizer, Hubert Wadepohl, and Lutz H. Gade
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Summary:The hydrazinediido complexes [Cp*M(NxylN)(NNPh2)(dmap)] (M = Zr, 3a; M = Hf, 3b; NxylN = 2-(N-xylylamino)pyrrolinate) have been synthesized, and their reactivity has been investigated. Both complexes were prepared from [Cp*M(NxylN)Cl2] (1a,b) and [Cp*M(NxylN)(NHNPh2)Cl] (2a,b), respectively, as precursors.
Item Description:Gesehen am 01.09.2020
Physical Description:Online Resource
ISSN:1520-6041
DOI:10.1021/om500087s

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