Gold-catalyzed intermolecular oxidative diyne cyclizations via 1,6-carbene transfer
A vinyl/α-oxo carbene is generated via an α-oxo carbene formation and subsequently transferred across the second alkyne. These highly active species can react with nitriles in an intermolecular fashion to provide substituted oxazoles. This methodology goes through 1,6-carbene shift and offers a rang...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2020
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| In: |
Advanced synthesis & catalysis
Year: 2019, Jahrgang: 362, Heft: 4, Pages: 755-759 |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201901318 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201901318 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201901318 
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| Verfasserangaben: | Qian Wang, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi |
| Zusammenfassung: | A vinyl/α-oxo carbene is generated via an α-oxo carbene formation and subsequently transferred across the second alkyne. These highly active species can react with nitriles in an intermolecular fashion to provide substituted oxazoles. This methodology goes through 1,6-carbene shift and offers a range of valuable products. |
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| Beschreibung: | Version of record online: November 27, 2019 Gesehen am 02.09.2020 |
| Beschreibung: | Online Resource |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201901318 |