Gold-catalyzed one-pot A3-coupling/1,5-hydride shift/Schmittel-type cyclization: from aldehydes, amines and alkynes to the synthesis of benzo[b]fluorenes
A short cut to anellated systems by gold catalysis is based on a combination of a gold‐catalyzed A3‐coupling followed by a 1,5‐hydride shift and a Schmittel‐type cyclization in a single synthetic operation.
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| Main Authors: | , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
02 January 2020
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| In: |
European journal of organic chemistry
Year: 2020, Issue: 9, Pages: 1160-1164 |
| ISSN: | 1099-0690 |
| DOI: | 10.1002/ejoc.201901906 |
| Online Access: | Resolving-System, kostenfrei, Volltext: https://doi.org/10.1002/ejoc.201901906 Verlag, kostenfrei, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201901906 |
| Author Notes: | Danilo M. Lustosa, Deborah Hartmann, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi |
| Summary: | A short cut to anellated systems by gold catalysis is based on a combination of a gold‐catalyzed A3‐coupling followed by a 1,5‐hydride shift and a Schmittel‐type cyclization in a single synthetic operation. |
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| Item Description: | Gesehen am 02.09.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1099-0690 |
| DOI: | 10.1002/ejoc.201901906 |