Gold-catalyzed one-pot A3-coupling/1,5-hydride shift/Schmittel-type cyclization: from aldehydes, amines and alkynes to the synthesis of benzo[b]fluorenes

A short cut to anellated systems by gold catalysis is based on a combination of a gold‐catalyzed A3‐coupling followed by a 1,5‐hydride shift and a Schmittel‐type cyclization in a single synthetic operation.

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Bibliographic Details
Main Authors: Lustosa, Danilo Machado (Author) , Hartmann, Deborah (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: 02 January 2020
In: European journal of organic chemistry
Year: 2020, Issue: 9, Pages: 1160-1164
ISSN:1099-0690
DOI:10.1002/ejoc.201901906
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Author Notes:Danilo M. Lustosa, Deborah Hartmann, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi
Description
Summary:A short cut to anellated systems by gold catalysis is based on a combination of a gold‐catalyzed A3‐coupling followed by a 1,5‐hydride shift and a Schmittel‐type cyclization in a single synthetic operation.
Item Description:Gesehen am 02.09.2020
Physical Description:Online Resource
ISSN:1099-0690
DOI:10.1002/ejoc.201901906