Mercury-free synthesis of pincer [C^N^C]AuIII complexes by an oxidative addition/CH activation cascade
Starting from the commercially available dimethyl sulfide‐gold(I) chloride complex (DMSAuCl) and diazonium salts in the presence of 2,6‐di‐tert‐butyl‐4‐methylpyridine as base, symmetric and unsymmetric [C^N^C]AuIIICl complexes were synthesized in a selective, photosensitizer‐free, photochemical reac...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
March 5, 2020
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| In: |
ChemSusChem
Year: 2020, Volume: 13, Issue: 8, Pages: 1986-1990 |
| ISSN: | 1864-564X |
| DOI: | 10.1002/cssc.202000310 |
| Online Access: | Resolving-System, kostenfrei, Volltext: https://doi.org/10.1002/cssc.202000310 Verlag, kostenfrei, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cssc.202000310 
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| Author Notes: | Daniel Eppel, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi |
| Summary: | Starting from the commercially available dimethyl sulfide‐gold(I) chloride complex (DMSAuCl) and diazonium salts in the presence of 2,6‐di‐tert‐butyl‐4‐methylpyridine as base, symmetric and unsymmetric [C^N^C]AuIIICl complexes were synthesized in a selective, photosensitizer‐free, photochemical reaction using blue LED light. This new protocol provides the first mercury‐free synthesis of these types of pincer‐complexes in moderate‐to‐excellent yields, starting from a readily available gold(I) precursor. |
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| Item Description: | Im Titel erscheint die Zeichenfolge III hochgestellt Version of record online: March 24, 2020 Gesehen am 02.09.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1864-564X |
| DOI: | 10.1002/cssc.202000310 |