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Structure-activity relationships of nickel-hexaaluminates in reforming reactions part I: controlling nickel nanoparticle growth and phase formation

Abstract: The controlled synthesis of hexaaluminates ANiyAl12?yO19?δ (A=Ba, La, Sr, and y=0.25, 0.5, 1) is reported by a freeze drying route. This route allows the use of moderate temperatures of approximately 1200?°C to obtain hexaaluminates of high phase purity (>80?wt?%) as well as high specif...

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Main Authors: Roussière, Thomas Luc (Author) , Schelkle, Korwin (Author) , Titlbach, Sven (Author) , Wasserschaff, Guido (Author) , Milanov, Andrian (Author) , Cox, Gerhard (Author) , Schwab, Ekkehard (Author) , Deutschmann, Olaf (Author) , Schulz, Linus (Author) , Jentys, Andreas (Author) , Lercher, Johannes (Author) , Schunk, Stephan A. (Author)
Format: Article (Journal)
Language:English
Published: March 24, 2014
In: ChemCatChem
Year: 2014, Volume: 6, Issue: 5, Pages: 1438-1446
ISSN:1867-3899
DOI:10.1002/cctc.201300960
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/cctc.201300960
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cctc.201300960
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Author Notes:Thomas Roussière, Korwin M. Schelkle, Sven Titlbach, Guido Wasserschaff, Andrian Milanov, Gerhard Cox, Ekkehard Schwab, Olaf Deutschmann, Linus Schulz, Andreas Jentys, Johannes Lercher, and Stephan A. Schunk
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Summary:Abstract: The controlled synthesis of hexaaluminates ANiyAl12?yO19?δ (A=Ba, La, Sr, and y=0.25, 0.5, 1) is reported by a freeze drying route. This route allows the use of moderate temperatures of approximately 1200?°C to obtain hexaaluminates of high phase purity (>80?wt?%) as well as high specific surface areas (10?30?m2?g?1). Under reducing conditions at elevated temperatures, nickel expulsion from the hexaaluminate framework can be observed. High stability of the crystalline phase is observed even if all substitution cations leave the hexaaluminate framework. The moderate calcination temperature of 1200?°C facilitates the reducibility of the Ni?hexaaluminates compared to Ni?hexaaluminates calcined at 1600?°C. SEM and TEM imaging revealed that Ni?hexaaluminates with low Ni loading (y=0.25) and calcined at moderate temperature (1200?°C) lead under reducing atmosphere to the formation of strong textural growth and highly disperse and highly textured Ni0 nanoparticles. Nanoparticle growth is associated to surface defect sites occurring on the hexaaluminate platelets.
Item Description:Gesehen am 03.09.2020
Physical Description:Online Resource
ISSN:1867-3899
DOI:10.1002/cctc.201300960

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