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Highly efficient gold-catalyzed synthesis of dibenzocycloheptatrienes

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Dibenzocycloheptatrienes are obtained by a gold-catalyzed 7-exo-dig hydroarylation protocol in a highly efficient manner. The gold-catalyzed reaction usually gives the products in high yields and excellent selectivity. This procedure provides an easy and efficient access to dibenzocycloheptanoids, w...

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Main Authors: Pflästerer, Daniel (Author) , Rettenmeier, Eva (Author) , Schneider, Severin (Author) , Heras Ruiz, Edgar de las (Author) , Rudolph, Matthias (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: April 25, 2014
In: Chemistry - a European journal
Year: 2014, Volume: 20, Issue: 22, Pages: 6752-6755
ISSN:1521-3765
DOI:10.1002/chem.201402015
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201402015
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201402015
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Author Notes:Daniel Pflästerer, Eva Rettenmeier, Severin Schneider, Edgar de Las Heras Ruiz, Matthias Rudolph, and A. Stephen K. Hashmi
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Summary:Dibenzocycloheptatrienes are obtained by a gold-catalyzed 7-exo-dig hydroarylation protocol in a highly efficient manner. The gold-catalyzed reaction usually gives the products in high yields and excellent selectivity. This procedure provides an easy and efficient access to dibenzocycloheptanoids, which are an interesting and unique class of natural products. This was underlined by the first total synthesis of reticuol.
Item Description:Gesehen am 22.09.2020
Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201402015

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