Synthesis of tetraazatetracenes and -pentacenes: role of the substituents for their stability
We report the synthesis of a series of novel tetraazaacene derivatives and compare their stability with respect to size, oxidation potential and position of the TIPS-ethynyl groups. The latter has the most pronounced effects on the stability. In case of azatetracenes where TIPS-alkynes are either at...
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| Main Authors: | , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
13.03.2014
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| In: |
Pure and applied chemistry
Year: 2014, Volume: 86, Issue: 4, Pages: 483-488 |
| ISSN: | 1365-3075 |
| DOI: | 10.1515/pac-2013-1211 |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1515/pac-2013-1211 Verlag, lizenzpflichtig, Volltext: https://www.degruyterbrill.com/view/journals/pac/86/4/article-p483.xml 
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| Author Notes: | Michaela Märken, Benjamin D. Lindner, Anthony L. Appleton, Frank Rominger and Uwe H.F. Bunz |
| Summary: | We report the synthesis of a series of novel tetraazaacene derivatives and compare their stability with respect to size, oxidation potential and position of the TIPS-ethynyl groups. The latter has the most pronounced effects on the stability. In case of azatetracenes where TIPS-alkynes are either attached laterally or in the peri-positions, the former ones dimerized while the latter are stable. Attempts to expand this concept to the corresponding tetrakis-peri-substituted heptacenes led to the isolation of the dimerized butterfly product. |
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| Item Description: | Gesehen am 29.09.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1365-3075 |
| DOI: | 10.1515/pac-2013-1211 |