Rigid π-extended triptycenes via a hexaketone precursor
A high-yielding synthesis of a rigid hexaketone is presented that can be transformed into π-extended D3h-symmetric triptycene derivatives with high internal molecular free volumes (IMFVs). The products show excellent photophysical properties combined with high specific surface areas.
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
13 January 2014
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| In: |
Organic letters
Year: 2014, Volume: 16, Issue: 3, Pages: 704-707 |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/ol403383y |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol403383y
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| Author Notes: | Bernd Kohl, Frank Rominger, and Michael Mastalerz |
| Summary: | A high-yielding synthesis of a rigid hexaketone is presented that can be transformed into π-extended D3h-symmetric triptycene derivatives with high internal molecular free volumes (IMFVs). The products show excellent photophysical properties combined with high specific surface areas. |
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| Item Description: | Gesehen am 06.10.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/ol403383y |