Rigid π-extended triptycenes via a hexaketone precursor
A high-yielding synthesis of a rigid hexaketone is presented that can be transformed into π-extended D3h-symmetric triptycene derivatives with high internal molecular free volumes (IMFVs). The products show excellent photophysical properties combined with high specific surface areas.
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
13 January 2014
|
| In: |
Organic letters
Year: 2014, Jahrgang: 16, Heft: 3, Pages: 704-707 |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/ol403383y |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol403383y
|
| Verfasserangaben: | Bernd Kohl, Frank Rominger, and Michael Mastalerz |
| Zusammenfassung: | A high-yielding synthesis of a rigid hexaketone is presented that can be transformed into π-extended D3h-symmetric triptycene derivatives with high internal molecular free volumes (IMFVs). The products show excellent photophysical properties combined with high specific surface areas. |
|---|---|
| Beschreibung: | Gesehen am 06.10.2020 |
| Beschreibung: | Online Resource |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/ol403383y |