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Rigid π-extended triptycenes via a hexaketone precursor

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A high-yielding synthesis of a rigid hexaketone is presented that can be transformed into π-extended D3h-symmetric triptycene derivatives with high internal molecular free volumes (IMFVs). The products show excellent photophysical properties combined with high specific surface areas.

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Bibliographic Details
Main Authors: Kohl, Bernd (Author) , Rominger, Frank (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: 13 January 2014
In: Organic letters
Year: 2014, Volume: 16, Issue: 3, Pages: 704-707
ISSN:1523-7052
DOI:10.1021/ol403383y
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol403383y
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Author Notes:Bernd Kohl, Frank Rominger, and Michael Mastalerz
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Modular two-step Access to π-extended naphthyridine systems: potent building blocks for organic electronics by Stuck, Fabian (Author) , Dietl, Martin C. (Author) , Meißner, Maximilian (Author) , Sebastian, Finn (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Krämer, Petra (Author) , Hashmi, A. Stephen K. (Author) ,


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Modularer zweistufiger Zugang zu π-erweiterten Naphthyridin-Systemen: potente Bausteine für die organische Elektronik by Stuck, Fabian (Author) , Dietl, Martin C. (Author) , Meißner, Maximilian (Author) , Sebastian, Finn (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Krämer, Petra (Author) , Hashmi, A. Stephen K. (Author) ,


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Die Kristallstrukturen aromatischer π [pi]-Systeme sowie deren Modifikation durch endständige Triptycen-Einheiten by Ueberricke, Lucas (Author)

2021

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