Mechanistic insights into the gold chemistry of allenes
Although most mechanistic studies on gold-catalysed reactions focused on alkynes as substrates, some knowledge about gold-catalysed conversions of allenic substrates has been obtained. This contribution summarises these insights into the reaction mechanisms of gold-catalysed transformations of allen...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
27 March 2014
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| In: |
Chemical Society reviews
Year: 2014, Volume: 43, Issue: 9, Pages: 2941-2955 |
| ISSN: | 1460-4744 |
| DOI: | 10.1039/C3CS60441A |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C3CS60441A Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2014/cs/c3cs60441a 
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| Author Notes: | Weibo Yang and A. Stephen K. Hashmi |
| Summary: | Although most mechanistic studies on gold-catalysed reactions focused on alkynes as substrates, some knowledge about gold-catalysed conversions of allenic substrates has been obtained. This contribution summarises these insights into the reaction mechanisms of gold-catalysed transformations of allenes which are based on computational studies, labelling studies, the detection of intermediates, chirality transfer and diastereoselective product formation. |
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| Item Description: | Gesehen am 09.10.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1460-4744 |
| DOI: | 10.1039/C3CS60441A |