Highly active phosphite gold(I) catalysts for intramolecular hydroalkoxylation, enyne cyclization and furanyne cyclization

New and highly active mononuclear phosphite gold(I) catalysts are described. Turn-over numbers up to 37 000 for the furan-yne reaction and up to 28 000 000 for the two-fold hydroalkoxylation of alkynes are reported.

Detalles Bibliográficos

Autores principales:	Blanco Jaimes, Maria Camila (Autor) , Rominger, Frank (Autor) , Pereira, Mariette M. (Autor) , Carrilho, Rui M. B. (Autor) , Carabineiro, Sónia A. C. (Autor) , Hashmi, A. Stephen K. (Autor)
Formato:	Article (Journal)
Lenguaje:	inglés
Publicado:	27 March 2014
In:	Chemical communications Year: 2014, Volumen: 50, Número: 38, Pages: 4937-4940
ISSN:	1364-548X
DOI:	10.1039/C4CC00839A
Acceso en línea:	Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C4CC00839A Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc00839a
Notas de Autor:	Maria Camila Blanco Jaimes, Frank Rominger, Mariette M. Pereira, Rui M. B. Carrilho, Sónia A.C. Carabineiro and A. Stephen K. Hashmi