Highly active phosphite gold(I) catalysts for intramolecular hydroalkoxylation, enyne cyclization and furanyne cyclization
New and highly active mononuclear phosphite gold(I) catalysts are described. Turn-over numbers up to 37 000 for the furan-yne reaction and up to 28 000 000 for the two-fold hydroalkoxylation of alkynes are reported.
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
27 March 2014
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| In: |
Chemical communications
Year: 2014, Volume: 50, Issue: 38, Pages: 4937-4940 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C4CC00839A |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C4CC00839A Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc00839a 
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| Author Notes: | Maria Camila Blanco Jaimes, Frank Rominger, Mariette M. Pereira, Rui M. B. Carrilho, Sónia A.C. Carabineiro and A. Stephen K. Hashmi |
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| 520 | |a New and highly active mononuclear phosphite gold(I) catalysts are described. Turn-over numbers up to 37 000 for the furan-yne reaction and up to 28 000 000 for the two-fold hydroalkoxylation of alkynes are reported. | ||
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