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Copper-boxmi complexes as highly enantioselective catalysts for electrophilic trifluoromethylthiolations

The enantioselective trifluoromethylthiolation of β-ketoesters using chiral copper-boxmi complexes as catalysts is reported. A number of α-SCF3-substituted β-ketoesters have been obtained with up to >99 % enantiomeric excess (ee), and the trifluoromethylthiolated products were then transformed di...

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Hauptverfasser: Deng, Qing-Hai (VerfasserIn) , Rettenmeier, Christoph Alexander (VerfasserIn) , Wadepohl, Hubert (VerfasserIn) , Gade, Lutz H. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2014
In: Chemistry - a European journal
Year: 2013, Jahrgang: 20, Heft: 1, Pages: 93-97
ISSN:1521-3765
DOI:10.1002/chem.201303641
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201303641
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201303641
Volltext
Verfasserangaben:Qing-Hai Deng, Christoph Rettenmeier, Hubert Wadepohl, and Lutz H. Gade

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