Synthesis of beltenes by reactions of 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctene with [CpCo(CO)2] derivatives

Cobalt studs the beltenes shown (R=H, CO2Me, SiMe3, 5 Me), which consist of annelated, conjugated four- and eight-membered rings. These strained molecules were synthesized in a one-pot reaction by a template supported trimerization of 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctene.

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Bibliographic Details
Main Authors: Hellbach, Björn (Author) , Rominger, Frank (Author) , Gleiter, Rolf (Author)
Format: Article (Journal)
Language:English
Published: 02 November 2004
In: Angewandte Chemie. International edition
Year: 2004, Volume: 43, Issue: 43, Pages: 5846-5849
ISSN:1521-3773
DOI:10.1002/anie.200460772
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.200460772
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200460772
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Author Notes:Björn Hellbach, Frank Rominger, and Rolf Gleiter
Description
Summary:Cobalt studs the beltenes shown (R=H, CO2Me, SiMe3, 5 Me), which consist of annelated, conjugated four- and eight-membered rings. These strained molecules were synthesized in a one-pot reaction by a template supported trimerization of 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctene.
Item Description:In der chemischen Formel CpCo(CO)2 erscheint die Ziffer 2 tiefgestellt
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Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.200460772