A stepwise degradation of sterically hindered CpCo-cyclobutadiene complexes
Sterically hindered CpCo stabilized cyclobutadiene complexes 4 were oxidized by ceric ammonium nitrate to yield the dinitratocobalt complexes 5. The thermolysis of 5a and the reaction of 5a with tert-butyl isocyanide as well as NaBH4 is reported.
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
9th November 2004
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| In: |
Dalton transactions
Year: 2004, Issue: 24, Pages: 4146-4151 |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/B412167H |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1039/B412167H Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2004/dt/b412167h 
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| Author Notes: | Carsten Schaefer, Rolf Gleiter and Frank Rominger |
| Summary: | Sterically hindered CpCo stabilized cyclobutadiene complexes 4 were oxidized by ceric ammonium nitrate to yield the dinitratocobalt complexes 5. The thermolysis of 5a and the reaction of 5a with tert-butyl isocyanide as well as NaBH4 is reported. |
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| Item Description: | Gesehen am 23.10.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/B412167H |